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2-D 納米黑卡室內(nèi)評(píng)價(jià)及縫洞型碳酸鹽巖油藏礦場(chǎng)應(yīng)用
梁拓,,侯吉瑞,,屈鳴,,張煒,,吳文明
1 中國(guó)石油大學(xué)(北京)非常規(guī)油氣科學(xué)技術(shù)研究院,北京 201149 2 中國(guó)石化西北油田分公司,,烏魯木齊 830011
2-D smart nanocard nanofluid laboratory evaluation and field application in fractured-vuggy carbonate reservoirs
LIANG Tuo , HOU Jirui , QU Ming, ZHANG Wei, WU Wenming
1 Unconventional Petroleum Research Institute, China University of Petroleum-Beijing, Beijing 102249, China 2 Sinopec Northwest China oilfield company, Urumqi 830011, China

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摘要? 塔河油田是國(guó)內(nèi)一種縫洞型碳酸鹽巖油藏,,具有巨大的開(kāi)發(fā)潛力和廣闊的開(kāi)發(fā)前景。針對(duì)塔河縫洞型碳 酸鹽巖油藏孔,、縫,、洞介質(zhì)發(fā)育且儲(chǔ)層非均質(zhì)性嚴(yán)重,天然能量底水開(kāi)發(fā)過(guò)程中易形成水錐,;注水開(kāi)發(fā)過(guò)程 中,,驅(qū)替介質(zhì)易從裂縫竄進(jìn)并產(chǎn)出,導(dǎo)致井間富集大量剩余油,,注水開(kāi)發(fā)效果差的問(wèn)題,;注氣過(guò)程中,易發(fā)生 氣竄等問(wèn)題,。為了克服以上問(wèn)題,,中國(guó)石油大學(xué)(北京)自主合成了具有親水—親油性的納米黑卡材料并開(kāi)展了 納米黑卡調(diào)驅(qū)潛力室內(nèi)實(shí)驗(yàn)研究。納米黑卡具有 95 nm橫向尺寸,,0.5~1.5 nm的厚度,。借助Turbiscan多重光散 射儀篩選出體系最穩(wěn)定的納米黑卡濃度為 50 mg/L;室內(nèi)靜態(tài)實(shí)驗(yàn)證明納米黑卡能夠?qū)ふ矣退缑娌⑿纬珊诳?吸附層,,改變界面性質(zhì),。再者,當(dāng)納米黑卡濃度為 50 mg/L時(shí),,油水界面張力達(dá)到 0.6 mN/m,,將模擬油乳化成 10~50 μm的穩(wěn)定乳狀液,也能夠?qū)⒂蜐袷⑵?116°)轉(zhuǎn)變成中性潤(rùn)濕(91.2°),。根據(jù)二維可視化微觀(guān)模型和細(xì)管 模型證明納米黑卡具有調(diào)驅(qū)的作用機(jī)理,,一維巖心驅(qū)替實(shí)驗(yàn)表明納米黑卡流體可使驅(qū)油效率增加 9.2%?;谑?內(nèi)評(píng)價(jià)結(jié)果,,初步在塔河TK779 井組開(kāi)展納米黑卡調(diào)驅(qū)先導(dǎo)性礦場(chǎng)試驗(yàn)。在注入 4900 m3 納米黑卡后(納米黑卡 濃度 50 mg/L),,三口鄰井顯著受效,,注入井組受效井累計(jì)增油 2233.9 t,平均含水從 82%降低至 25.7%,。納米黑 卡調(diào)驅(qū)作為一種高效,、低廉的調(diào)驅(qū)技術(shù),有望為縫洞型碳酸鹽巖油藏后期開(kāi)發(fā)提供重要的技術(shù)支持,。
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關(guān)鍵詞 : 納米黑卡;界面性質(zhì),;乳化,;潤(rùn)濕反轉(zhuǎn);調(diào)驅(qū)結(jié)合,;縫洞型碳酸鹽巖油藏
Abstract

    Tahe oilfield, a fractured-vuggy carbonate reservoir in China, has great potential and broad prospects during its oil    development stage. The full development of holes, fractures and vugs in fractured-vuggy carbonate reservoirs in the Tahe oilfield    results in high heterogeneity. The water cone is easily formed during natural energy bottom water development. The displacement    aqueous solution is easily produced along the fractures, causing more remaining oil among wells and a poor result of water    flooding. It is easy to form gas channels during gas injection development. To overcome the issues mentioned above, a smart    nanocard nanofluid with hydrophilicity-lipophilicity was synthesized independently by China University of Petroleum (Beijing) and then utilized to study the ability of profile control and flooding in the laboratory. Smart nanocard is a kind of nano-flake material with sizes of 95 nm in plane and 0.5~1.5 nm in height. The Turbiscan scatterometer was used to evaluate the stability of the smart nanocard nanofluid. The result demonstrated the system was most stable when the concentration of smart nanocard was 50 mg/L. In addition, laboratory experiment results proved that the smart nanocard could intelligently find the oil-water interface and form smart nanocard adsorption layers to change the interface properties. Moreover, the interfacial tension reached 0.6 mN/m and stable emulsions in size of 10 to 50 μm were also formed between simulated oil and water phases when the concentration of the smart nanocard was 50 mg/L. It is also worth mentioning that an oil-wet quartz sheet (contact angle~116°) was transferred into neutral wet (contact angle ~91°). It was also proved that smart nanocard has a mechanism of profile control and flooding according to the results derived from a 2D visualization model and a thin tube model. Besides, it demonstrated that oil displacement efficiency was increased by 9.2 % after smart nanocard flooding in core. Based on the laboratory results, a field test of smart nanocard profile control and flooding technology was initially carried out in the TK779 well groups in Tahe oilfield. Three adjacent wells were significantly affected after 4900 m 3  smart nanocard aqueous solutions were injected (smart nanocard concentration~50 mg/L). The three affected wells increased oil by 2233.9 tons and the average water content decreased from 82to 25.7 % . Smart nanocard intelligent profile control and flooding technology, as an economical and high efficiency enhanced oil recovery technology, is expected to provide important technical support for the development of later stage fractured-vuggy carbonate reservoirs.     


Key words: smart nanocard; interfacial properties; emulsions; wettability alteration; profile control and flooding; fractured-vuggy carbonate reservoirs
收稿日期: 2020-09-29 ????
PACS: ? ?
基金資助:國(guó)家重大專(zhuān)項(xiàng)“縫洞型碳酸鹽巖油藏提高采收率關(guān)鍵技術(shù)”( 項(xiàng)目編號(hào) 2016ZX05014) 和國(guó)家重大專(zhuān)項(xiàng)“低滲- 致密油藏高效提高采收率
技術(shù)”( 項(xiàng)目編號(hào) 2017ZX05009) 聯(lián)合資助
通訊作者: [email protected]
引用本文: ??
LIANG Tuo, HOU Jirui, QU Ming, ZHANG Wei, WU Wenming. 2-D smart nanocard nanofluid laboratory evaluation and field application in fractured-vuggy carbonate reservoirs. Petroleum Science Bulletin, 2020, 03: 402-411.
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