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首頁» 過刊瀏覽» 2017» Vol. 2» Issue (4) 527-535???? DOI : 10.3969/j.issn.2096-1693.2017.04.049
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多孔介質(zhì)中二元復(fù)合體系乳化前后流動規(guī)律研究
劉哲宇1, 2,,李宜強1, 2*,,莊永濤3,,陳一航4,,馬瑞程4
1 中國石油大學(北京)石油工程學院,,北京 102249 2 中國石油大學石油工程教育部重點實驗室,,北京 102249 3 大港油田采油工藝研究院,,天津 300280 4 中國石油大學(北京)提高采收率研究院,,北京 102249
Comparison of a surfactant/polymer solution and its emulsion flowing in a porous medium
LIU Zheyu1,2, LI Yiqiang1,2, ZHUANG Yongtao3, CHEN Yihang4, MA Ruicheng4
1 College of Petroleum Engineering, China University of Petroleum-Beijing, Beijing 102249, China 2 State Key Laboratory of Petroleum Engineering, China University of Petroleum-Beijing, Beijing 102249, China 3 Oil Production Technology Institute, Dagang Oilfield Company, Tianjin 300280,China 4 Research Institute of EOR, China University of Petroleum-Beijing, Beijing 102249, China

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摘要? 復(fù)合驅(qū)過程中出現(xiàn)的乳化現(xiàn)象直接影響開發(fā)效果,,目前對復(fù)合體系乳化后形成的乳狀液的流動規(guī)律缺少相關(guān)研究,。本文采用巖心實驗分別注入O/W型乳狀液與等黏度的二元體系,,測定采出液的流變性、粒度分布以及乳狀液液滴形態(tài),,比較它們在多孔介質(zhì)中的流動規(guī)律差異,,再通過多孔介質(zhì)模擬復(fù)合驅(qū)過程中乳狀液的產(chǎn)生過程,通過壓力變化研究各因素對體系乳化強度的影響,。結(jié)果表明,,二元體系乳化前后的運移規(guī)律存在明顯差異,乳化前體系的壓力可以很快達到平穩(wěn),,而乳化后的壓力呈現(xiàn)跳躍上升,,既表現(xiàn)出冪律流體剪切變稀的特性,又由于分散性質(zhì)加強而表現(xiàn)出剪切變稠的特征,;采出液分析表明經(jīng)過巖心后,,乳狀液的流變曲線上移,粒徑變小,,經(jīng)過3?PV后乳狀液的液滴形態(tài)才與初始時相似,;各因素中表面活性劑濃度對乳化效果的影響大于剪切速率,含油飽和度對乳化效果的影響最小,。
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關(guān)鍵詞 : 二元復(fù)合驅(qū), 乳狀液, 滲流規(guī)律, 流變性, 多孔介質(zhì)
Abstract

  The emulsion generated during combination flooding has a big impact on oil recovery. Unfortunately, there has been a lack of emulsion flow research. Core flow experiments were used to investigate the flow difference between oil in water emulsion and surfactant/polymer solution, which have the same viscosity by measuring pressure, rheological properties, particle size distribution and emulsion droplet morphology of the effluent. Meanwhile, surfactant polymer (SP) solution and oil was co-injected into a core to generate an emulsion. Impacts on emulsion flow properties, such as oil water ratio, surfactant concentration and flow velocity were investigated by comparing pressure curves. The results showed that there were significant flow differences between the SP solution and its generated emulsion. The pressure of the SP solution quickly achieved a steady level. However, the emulsion showed jamming and drop breakup phenomena. The rheology of the emulsion was not only shear thinning, but also shear thickening because pore throat shearing increased its dispersion. The analysis of effluent indicated that as the viscosity of the emulsion increased, the droplet size decreased and the emulsion morphology become similar to its initial status after 3PV. The surfactant concentration has more effect than shear rate on the emulsification, while the oil saturation has a minimal effect.

Key words: surfactant/polymer flooding emulsion percolation rule rheology porous medium
收稿日期: 2017-08-08 ????
PACS: ? ?
基金資助:國家科技重大專項(2016ZX05025-003-010)和中國石油大學優(yōu)秀博士學位論文基金項目(01JB0585)聯(lián)合資助
通訊作者: 李宜強, [email protected]
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劉哲宇,,李宜強,,莊永濤,陳一航,,馬瑞程. 多孔介質(zhì)中二元復(fù)合體系乳化前后流動規(guī)律研究[J]. 石油科學通報, 2017, 2(4): 527-535. LIU Zheyu, LI Yiqiang, ZHUANG Yongtao, CHEN Yihang, MA Ruicheng. Comparison of a surfactant/polymer solution and its emulsion flowing in a porous medium. Petroleum Science Bulletin, 2017, 2(4): 527-535.
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