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首頁» 過刊瀏覽» 2021» Vol.6» Issue(3) 516-523???? DOI : 10.3969/j.issn.2096-1693.2021.03.042
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無機土壤修復劑對石油烴污染物治理機理研究與驗證
劉銳鋒
大慶石油管理局鉆探工程公司試油測試公司,,吉林松原 138000
Research and verification of the treatment mechanism of inorganic soil remediation agent for petroleum hydrocarbon pollutants
LIU Ruifeng
Oil Testing Company of Daqing Oilfield Drilling Engineering Company, CNPC, Songyuan 138000, Jilin, China

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摘要? 為了解決油田開發(fā)中的石油烴土壤污染問題,,創(chuàng)新性地將氧化鎂作為修復劑配方成分,對其與粉煤灰,、 氧化鈣配伍進行石油烴污染修復的可行性,,從機理方面進行了研究與分析,,認為氧化鎂粉具有很大的比表面積 和豐富的孔結(jié)構(gòu),煤灰提供大量Al,、Si等活性位點,,氧化鎂與氧化鈣的堿性作用,會協(xié)同將石油烴吸附并形成 穩(wěn)定的化合物,,且該過程具有不可逆性,,從而達到石油烴污染土壤修復的目的。為了驗證上述機理,,以吉林油 田扶余和紅崗采油廠原油為污染物,,通過調(diào)整 3 種成分的配比,實驗研究修復劑對石油烴污染土壤的修復效果,, 結(jié)果表明:對于扶余原油最佳復配質(zhì)量比為氧化鈣:氧化鎂:粉煤灰=4:5:3,,對于紅崗原油最佳復配質(zhì)量比為氧 化鈣:氧化鎂:粉煤灰=3:3:2,修復效率在 85%以上,。通過機理研究與驗證實驗,,認為本研究的無機土壤修復劑 對石油烴污染物具有很好的去除效果,且修復劑成本低廉,,綠色環(huán)保,,是一種很有發(fā)展前景的石油烴污染土壤 修復技術。
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關鍵詞 : 無機修復劑,;石油污泥;固化吸附,;環(huán)境保護,;原位修復
Abstract
In order to solve the problem of petroleum hydrocarbon soil pollution in oilfield development, the feasibility of using    
magnesium oxide as a remediation agent formula component, and its compatibility with fly ash and calcium oxide for petroleum    
hydrocarbon pollution remediation, was studied.. According to analysis, it is believed that magnesium oxide powder has a large    
specific surface area and rich pore structure. Coal fly ash provides a large number of active sites such as Al and Si. The alkaline    
effect of magnesium oxide and calcium oxide will synergistically adsorb petroleum hydrocarbons and form a stable mixture. The    
process is irreversible, so it achieves the purpose of remediation of petroleum contaminated soil. In order to verify the above    
mechanism, using crude oil from Fuyu and Honggang Oil Production Plants in Jilin Oilfield as pollutants, by adjusting the ratio    
of three components, the experimental study of the remediation effect of the remediation agent on petroleum contaminated soil    
shows that: the best ratio for Fuyu oil is calcium oxide: magnesium oxide: fly ash is 4:5:3. The best mixed mass ratio for Hong  
gang crude oil is calcium oxide: magnesium oxide: fly ash 3:3:2, and the repair efficiency is 85   %   .. Through mechanism research    
and verification experiments, it is believed that the inorganic soil remediation agent in this study has a good removal effect on    
petroleum hydrocarbon pollutants, and the remediation agent is low in cost and environmentally friendly, and is a promising  
petroleum hydrocarbon contaminated soil remediation technology  


Key words: inorganic repair agent; petroleum sludge; curing adsorption; environmental protection; in-situ remediation
收稿日期: 2021-09-29 ????
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通訊作者: [email protected]
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劉銳鋒. 無機土壤修復劑對石油烴污染物治理機理研究與驗證. 石油科學通報, 2021, 03: 516-523 LIU Ruifeng. Research and verification of the treatment mechanism of inorganic soil remediation agent for petroleum hydrocarbon pollutants. Petroleum Science Bulletin, 2021, 03: 516-523.
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