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首頁(yè)» 過(guò)刊瀏覽» 2021» Vol.6» Issue(1) 1-15???? DOI : 10.3969/j.issn.2096-1693.2021.01.001
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準(zhǔn)噶爾盆地阜東斜坡梧桐溝組儲(chǔ)層沸石分布特征及成因機(jī)制
史燕青,,季漢成,,張國(guó)一 ,王劍,,宋興國(guó),劉盡賢
1 中國(guó)石油大學(xué)(北京)地球科學(xué)學(xué)院,,北京 102249 2 中國(guó)石油大學(xué)(北京)油氣資源與探測(cè)國(guó)家重點(diǎn)實(shí)驗(yàn)室,,北京 102249 3 中國(guó)石油吉林油田勘探開(kāi)發(fā)研究院,吉林松原 138000 4 中國(guó)石油新疆油田公司實(shí)驗(yàn)檢測(cè)研究院,,新疆克拉瑪依 834000 5 中國(guó)石化集團(tuán)華東油氣分公司泰州采油廠,,江蘇泰州 225300
Characteristics and genetic mechanisms of widely distributed zeolites in the Wutonggou Formation reservoir in the southern Junggar Basin
SHI Yanqing, JI Hancheng, ZHANG Guoy , WANG Jian , SONG Xingguo, LIU Jinxian
College of Geosciences, China University of Petroleum-Beijing, Beijing 102249, China 2 State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum-Beijing, Beijing 102249, China 3 Exploration & Development Research Institute, PetroChina Jilin Oilfield Company, Sonyuan 138000, China 4 Research Institute of Experiment and Detection, PetroChina Xinjiang Oilfield Company, Karamay 834000, China 5 Oil Production Plant of East China Branch Company, SINOPEC, Taizhou 225300, China

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摘要? 準(zhǔn)噶爾盆地南部阜康凹陷東斜坡上二疊統(tǒng)梧桐溝組儲(chǔ)層富含多種類(lèi)型的沸石。沸石類(lèi)礦物通常在碎屑巖,、 特別是火山碎屑巖中集中發(fā)育,。沸石對(duì)油氣儲(chǔ)層的儲(chǔ)集性能具有重要的影響,但其成因機(jī)制仍存在爭(zhēng)議,。本研 究利用掃描電鏡,、電子探針和光學(xué)顯微鏡識(shí)別了梧桐溝組的主要 4 種沸石類(lèi)型:濁沸石、方沸石,,部分片沸石 以及少量斜發(fā)沸石,。濁沸石和方沸石在研究區(qū)梧桐溝組含量較高,分別占沸石總含量的 60%和 30%,,片沸石則 相對(duì)含量較少,,斜發(fā)沸石含量最少。阜東斜坡梧桐溝組沸石的分布特征主要受沉積微相,、物源,、地層水性質(zhì)等 因素的影響。在水下分流河道,、河口壩等儲(chǔ)層物性發(fā)育較好的微相中,,沸石含量越高,;并且在靠近南部博格達(dá) 山物源區(qū)的地區(qū),有利于沸石的發(fā)育,,沸石含量高,。此外,在CaCl2 型地層水環(huán)境下,,沸石的含量(主要為濁沸 石)明顯高于其它地層水環(huán)境,。在高沸石含量的情況下(大于 5%),沸石的含量與孔隙度,、滲透率呈負(fù)相關(guān)關(guān)系,, 表明沸石膠結(jié)物的溶蝕作用對(duì)儲(chǔ)層的物性和儲(chǔ)集性能具有明顯的改善作用。目前主流觀點(diǎn)認(rèn)為準(zhǔn)噶爾盆地二疊 系的沸石是由火山物質(zhì)蝕變并依次轉(zhuǎn)化而來(lái),,近期的研究中,,將準(zhǔn)西北緣二疊系的沸石劃分為高溫成因和低溫 成因兩種,高溫成因是由凝灰物質(zhì)蝕變轉(zhuǎn)化而來(lái),,低溫成因則是由孔隙水結(jié)晶形成,。早期的濁沸石遭受酸性流 體的溶蝕,后期孔隙水在溶蝕孔隙中富集結(jié)晶形成第二期沸石,。不同于傳統(tǒng)意義上“火山物質(zhì)水化”和沸石之 間相互轉(zhuǎn)化,,通過(guò)掃描電鏡和能譜分析,阜東斜坡梧桐溝組的沸石產(chǎn)生與長(zhǎng)石的轉(zhuǎn)化密切相關(guān),,其中濁沸石和 片沸石主要來(lái)自于斜長(zhǎng)石在堿性條件下的鈉長(zhǎng)石化,,而方沸石則可能來(lái)自于鉀長(zhǎng)石在堿性條件下的轉(zhuǎn)化作用。
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關(guān)鍵詞 : 準(zhǔn)噶爾盆地;梧桐溝組,;沸石,;溶蝕;形成機(jī)制
Abstract
Widely distributed zeolites were identified in the upper Permian Wutonggou Formation in the east slope of the Fukang sag of the southern Junggar Basin, NW China. Zeolites are usually found in clastic rocks, especially in pyroclastic rocks. Zeolite has an important influence on the reservoir properties of oil and gas reservoirs, however, the genetic mechanisms are still controversial. Four types of zeolites were identified by using scanning electron microscopy (SEM), electron microprobe analysis and optical microscopy. The content of laumontite and analcite are greater in the study area, accounting for 60% and 30% of total zeolite, while the content of heulandite is relatively lower, and clinoptilolite the lowest. The distribution characteristics of zeolites in the Wutonggou    
Formation are mainly affected by sedimentary microfacies, provenance and stratum water properties. There is more zeolite in the microfacies with better physical reservoir properties, such as subaqueous distributary channels and river mouth bars in a deltaic sedimentary environment. And in the area close to the southern Bogda mountain source area, this is beneficial to the formation of  zeolites. Meanwhile, in the CaCl2 stratum water environment, the content of zeolites (mainly laumontite) is obviously higher than that in other stratum water environments. When the zeolite content is greater than 5%, the content of zeolite is negatively correlated with porosity and permeability, indicating that the dissolution of zeolite cement could significantly improve the physical properties    
and storage performance of the reservoir. It is generally accepted that Permian zeolites in the Junggar Basin are derived from volcanic material alteration. In a recent study, zeolites in the study area are subdivided using the two kinds of genetic mechanisms, high and low temperature. The high temperature genetic mechanism is related to the alteration of tuff material, while the low temperature genetic mechanism is considered as crystallization caused by pore water. In the early stage, zeolite was dissolved by acid fluid; and in the later stage, pore water was enriched and crystallized to form the second stage zeolite. SEM images and energy-dispersive X-ray analysis show that it is different from the traditional sense of volcanic material hydration and zeolites transformed into other zeolite minerals. Zeolites in the Wutonggou Formation are more likely related to the transformation of different types of feldspars. Laumonite and heulandite mainly come from the albitization of plagioclase in an alkaline diagenetic environment, whereas analcime may come from the conversion of potassium feldspar in alkaline conditions.  


Key words: Junggar Basin; Wutonggou Formation; zeolites; dissolution; formation mechanism
收稿日期: 2021-03-30 ????
PACS: ? ?
基金資助:中國(guó)石油天然氣集團(tuán)有限公司—中國(guó)石油大學(xué)( 北京) 戰(zhàn)略合作科技專(zhuān)項(xiàng)(ZLZX2020-01) 資助
通訊作者: [email protected]
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SHI Yanqing, JI Hancheng, ZHANG Guoyi, WANG Jian, SONG Xingguo, LIU Jinxian. Characteristics and genetic mechanisms of widely distributed zeolites in the Wutonggou Formation reservoir in the southern Junggar Basin. Petroleum Science Bulletin, 2021, 01: 1-15.
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