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首頁(yè)» 過(guò)刊瀏覽» 2020» Vol.5» Issue(3) 299-315???? DOI : 10.3969/j.issn.2096-1693.2020.03.026
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淺表沉積有機(jī)質(zhì)生烴特征研究現(xiàn)狀及發(fā)展趨勢(shì)
牛琮凱,,姜福杰
1 中國(guó)石油大學(xué)(北京) 油氣資源與探測(cè)國(guó)家重點(diǎn)實(shí)驗(yàn)室,,北京 102249 2 中國(guó)石油大學(xué)(北京) 地球科學(xué)學(xué)院,,北京 102249 3 中國(guó)地質(zhì)大學(xué)(北京) 能源學(xué)院,,北京 100083
An overview of hydrocarbon generation from shallow sedimentary organic matter: Current status and future prospects
NIU Congkai, JIANG Fujie
1 State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum-Beijing, Beijing 102249, China 2 College of Geosciences, China University of Petroleum-Beijing, Beijing 102249, China 3 School of Energy Resources, China University of Geosciences-Beijing, Beijing 100083, China

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摘要? 油氣成因理論一直在不斷發(fā)展,,盡管目前以干酪根晚期熱降解為主導(dǎo)的生烴理論已被大多數(shù)學(xué)者所接受,, 但是對(duì)于有機(jī)質(zhì)在未熟—低熟情況下能否向油氣轉(zhuǎn)化及其轉(zhuǎn)化的能力,,一直沒(méi)有形成系統(tǒng)的認(rèn)識(shí),。本文系統(tǒng)查 閱了國(guó)內(nèi)外對(duì)第四系沉積物和現(xiàn)代生物生烴特征相關(guān)研究文獻(xiàn),總結(jié)了淺表沉積有機(jī)質(zhì)來(lái)源,、生烴潛力,、生烴 模式等方面的認(rèn)識(shí),并提出淺表沉積有機(jī)質(zhì)生烴發(fā)展趨勢(shì)和建議?,F(xiàn)代沉積物中存在豐富的可溶有機(jī)質(zhì),,僅有 0.1%~2%的初級(jí)生產(chǎn)有機(jī)質(zhì)進(jìn)入到成巖后期階段,其中脂肪酸是未熟—低成熟階段向液態(tài)烴轉(zhuǎn)化的重要物質(zhì),,藻 類,、樹(shù)脂、孢粉的熱模擬實(shí)驗(yàn)顯示特殊有機(jī)質(zhì)的類脂物在低溫催化作用下不需要經(jīng)歷干酪根階段就可以向液態(tài)產(chǎn) 物轉(zhuǎn)化,,熱解產(chǎn)物顯示為瀝青質(zhì)和膠質(zhì)含量遠(yuǎn)高于總烴含量的特征,,并且極性組分不斷向總烴組分轉(zhuǎn)化,生烴路 徑表現(xiàn)為生物原生有機(jī)質(zhì)向可溶有機(jī)質(zhì)轉(zhuǎn)化,、可溶有機(jī)質(zhì)脫雜原子官能團(tuán)向烴類演化,,現(xiàn)代生物生烴總結(jié)為 4 個(gè) 階段,,即原始狀態(tài)、早期成烴,、成烴高峰,、成烴后期??傮w而言,,對(duì)于現(xiàn)代沉積有機(jī)質(zhì)生烴機(jī)理、模式和能力的 研究相對(duì)薄弱,,目前研究主要針對(duì)某一種單一或多種原始生命體,,缺少對(duì)原始生命體自沉積開(kāi)始進(jìn)入到生烴門限 階段的演化過(guò)程與生烴轉(zhuǎn)化的機(jī)理性認(rèn)識(shí),并且研究手段仍依賴于有機(jī)質(zhì)熱模擬,,以溫度為主控因素,,忽略了可 溶有機(jī)質(zhì)受到的綜合地質(zhì)作用,建議未來(lái)立足于現(xiàn)代海洋或湖盆沉積,,發(fā)展成巖過(guò)程實(shí)驗(yàn)與生烴過(guò)程等檢測(cè)技 術(shù),,完善原始生命體自沉積后到進(jìn)入生烴門限過(guò)程的生烴演化機(jī)理,加強(qiáng)現(xiàn)代沉積有機(jī)質(zhì)生烴過(guò)程的系統(tǒng)模擬和 生成產(chǎn)物的后期演化分析,,以完善有機(jī)質(zhì)生烴理論,,為油氣資源評(píng)價(jià)提供更有力的理論支撐。
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關(guān)鍵詞 : 淺表沉積物;特殊有機(jī)質(zhì),;生烴能力,;成烴演化;生烴理論
Abstract

The understanding of hydrocarbon generation has been continuously developed. Although hydrocarbon generation through kerogen late thermal degradation has been widely accepted by most scholars, there has been no systematic understanding of whether organic matter can be converted to oil and gas under immature conditions. This paper systematically reviewed hydrocarbon generation characteristics of Quaternary sediments and modern biology in China and abroad, and summarized the understanding of organic matter sources of shallow sediments, hydrocarbon generation potentials, and hydrocarbon generation models, investigating the development trends and suggestions of shallow sediment hydrocarbon generation characteristics. There is abundant soluble organic matter in modern sediments, and only 0.1%~2% of primary organic matter is preserved into the late diagenetic stage, among which fatty acids are an important material to transform into liquid hydrocarbon in an immature stage. The thermal simulation experiments of algae, resin and sporopollen show that lipids of special organic matter can be transformed into liquid product without undergoing a kerogen stage under low temperature catalysis. The pyrolysis products show that the content of asphaltene and resin is much higher than that of total hydrocarbon, and polar fractions are continuously transformed into total hydrocarbon fractions. The hydrocarbon generation path is the transformation of primary organic matter into soluble organic matter, and evolution of soluble organic matter into hydrocarbon by removing the heteroatom functional groups. Furthermore, the hydrocarbon generation of modern organisms can be divided into four stages, i.e., original stage, early hydrocarbon generation, hydrocarbon generation peak and late hydrocarbon generation. However, the research into the mechanism, model and ability of hydrocarbon generation of modern sediments is relatively weak. At present, the research mainly focuses on single or multiple primitive organisms and lacks the mechanism recognition of evolutionary process and hydrocarbon generation transformation of primitive organisms from the beginning of sedimentation to the hydrocarbon generation threshold, and research methods still rely on the thermal simulation of organic matter, with temperature as the main controlling factor, but ignore the comprehensive geological process of soluble organic matter. It is suggested to develop diagenetic process experiments and isochronous detection technologies for hydrocarbon generation processes based on modern marine or lake deposition in the future, and improve the hydrocarbon generation mechanism from deposition to hydrocarbon generation threshold, strengthening the systematic simulation of the hydrocarbon generation process of modern sediments and the late evolution analysis of the products, in order to improve the understanding of hydrocarbon generation and provide more powerful theoretical support for the evaluation of oil and gas resources.  

 

 

 
 
Key words: shallow sediments; special organic matter; hydrocarbon generating capacity; generating hydrocarbon and evolution; hydrocarbon generation theory
收稿日期: 2020-09-28 ????
PACS: ? ?
基金資助:國(guó)家自然科學(xué)基金面上項(xiàng)目(41872128),、頁(yè)巖油氣富集機(jī)理與有效開(kāi)發(fā)國(guó)家重點(diǎn)實(shí)驗(yàn)室開(kāi)放基金項(xiàng)目(G5800-19-ZS-KFGY005) 資助
通訊作者: [email protected]
引用本文: ??
NIU Congkai, JIANG Fujie. An overview of hydrocarbon generation from shallow sedimentary organic matter: Current status and future prospects. Petroleum Science Bulletin, 2020, 03: 299-315.
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