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首頁» 過刊瀏覽» 2019» Vol.4» Issue(4) 440-449???? DOI : 10.3969/j.issn.2096-1693.2019.04.039
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基于瀝青SARA組成的SBS改性瀝青高溫性能研究
王勤芳1,,曾海2*,楊耀1
1 中國石油大學(xué)( 北京) 化學(xué)工程與環(huán)境學(xué)院,,北京102249 2 中國石油遼河石化分公司,,盤錦 124022
High-temperature performance study of SBS modified asphalt based on SARA fractions
WANG Qinfang1, ZENG Hai2, YANG Yao1
1 College of Chemical Engineering and Environment, China University of Petroleum-Beijing, Beijing 102249, China 2 PetroChina Liaohe Petrochemical Company, Panjin 124022, China

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摘要? 本文選取4種不同油源的基質(zhì)瀝青,采用高速剪切法制備苯乙烯-丁二烯-苯乙烯嵌段共聚物(SBS)改性瀝青,,通過瀝青軟化點(diǎn)試驗(yàn),、動態(tài)剪切流變試驗(yàn)(DSR)以及多重應(yīng)力蠕變恢復(fù)試驗(yàn)(MSCR)考察了SBS劑量與基質(zhì)瀝青四組分(SARA)組成對改性瀝青高溫性能的影響。結(jié)果發(fā)現(xiàn),,改性瀝青的高溫性能隨著SBS劑量的增加而不斷增強(qiáng),;基質(zhì)瀝青中瀝青質(zhì)含量高,飽和分含量低時,,改性后高溫性能更好,,而飽和分含量較高時,改性瀝青的高溫性能隨SBS劑量的增加改善速度更快,;基質(zhì)瀝青對改性瀝青高溫性能的影響在SBS劑量較低時顯著,,而SBS劑量較高時,SBS對改性瀝青高溫性能的影響更加明顯,;在DSR試驗(yàn)中SBS劑量為5.0%,,低測試角頻率(0.1~1.0 rad/s),測試溫度為70℃時,,III號瀝青改性后的抗流動變形能力最好,;動態(tài)剪切流變試驗(yàn)和多重應(yīng)力蠕變恢復(fù)試驗(yàn)在評價改性瀝青高溫性能時有較好的相關(guān)性。
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關(guān)鍵詞 : SBS改性劑;基質(zhì)瀝青,;改性瀝青,;車轍因子;高溫性能
Abstract

In this study, four kinds of neat asphalt with different oil sources were selected, and Styrene–Butadiene–Styrene(SBS) modified asphalt was prepared by a high shear method. This study was to investigate the influence of the separation of four SARA fractions and the dosage of SBS polymer on the high temperature performance of modified asphalt in the Softening Point test, Dynamic Shear Rheometer (DSR) and Multiple Stress Creep Recovery (MSCR). The results revealed that the dosage of SBS polymer and SARA fractions had significant effects on the high-temperature performance of modified asphalt. With increasing dosage of SBS polymer, the high-temperature performance of modified asphalt improved continuously. The higher the content of asphaltenes and the lower the content of saturates , the better the high-temperature performance of SBS modified asphalt. The results also indicated that a high saturates content can cause the high-temperature performance of the modified asphalt to improve faster with an increase of the SBS polymer. When the dosage of SBS polymer was low, the neat asphalt has a significant effect on the high temperature performance of the modified asphalt, whereas the influence of SBS polymer is more obvious. The anti-flow deformation ability of III-SBS modified asphalt was the best at high SBS dosage (5.0%), low test oscillation frequency (0.1 ~ 1.0 rad/s) and high test temperature (70 ℃). The dynamic Shear Rheological test and Multiple Stress Creep Recovery test had a good positive correlation on evaluating the SBS modified asphalt.

Key words: SBS modifier, neat asphalt, modified asphalt, high-temperature performance
收稿日期: 2019-12-30 ????
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通訊作者: [email protected]
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王勤芳, 曾海, 楊耀. 基于瀝青SARA組成的SBS改性瀝青高溫性能研究. 石油科學(xué)通報, 2019, 04: 440-449
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WANG Qinfang, ZENG Hai, YANG Yao. High-temperature performance study of SBS modified asphalt based on SARA fractions. Petroleum Science Bulletin, 2019, 04: 440-449.
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