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首頁» 過刊瀏覽» 2017» Vol. 2» Issue (3) 422-430???? DOI : 10.3969/j.issn.2096-1693.2017.03.039
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濕度對(duì)CH4/CO2在干酪根中吸附的影響:分子模擬研究
黃亮1,2 寧正福1,2,王慶1,2,,秦慧博3,,葉洪濤1,2,張文通1,2,,李鐘原1,2孫一丹1,2
1 中國石油大學(xué)(北京)油氣資源與探測(cè)國家重點(diǎn)實(shí)驗(yàn)室,北京 102249 2 中國石油大學(xué)(北京)石油工程學(xué)院,,北京 102249 3 中國石油大學(xué)(北京)重質(zhì)油國家重點(diǎn)實(shí)驗(yàn)室,,北京 102249
Effect of moisture on CH4/CO2 adsorption on kerogen: A molecular simulation study
HUANG Liang1,2, NING Zhengfu1,2, WANG Qing1,2, QIN Huibo3, YE Hongtao1,2, ZHANG Wentong1,2, LI Zhongyuan1,2, SUN Yidan1,2
1 State Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum-Beijing, Beijing 102249, China 2 School of Petroleum Engineering, China University of Petroleum-Beijing, Beijing 102249, China 3 State Key Laboratory of Heavy Oil Processing, China University of Petroleum-Beijing, Beijing 102249, China

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摘要? CH4和CO2在不同濕度頁巖干酪根中的吸附行為對(duì)頁巖CO2埋存具有重要指導(dǎo)意義。本文采用分子動(dòng)力學(xué)(MD)方法構(gòu)建和優(yōu)化干燥的干酪根模型,,采用巨正則蒙托卡羅(GCMC)方法構(gòu)建不同濕度含量的干酪根模型,,并模擬CH4、CO2單組分及其混合氣體在干酪根模型中的吸附行為,。通過分析濕度對(duì)CH4和CO2吸附量,、等量吸附熱和吸附選擇性的影響,對(duì)頁巖CO2埋存提高氣體采收率的潛在可行性進(jìn)行了探討,。研究發(fā)現(xiàn):①水分子在高濕度下易形成籠形團(tuán)簇結(jié)構(gòu),,惡化CO2置換CH4的效果;②頁巖CO2埋存提高CH4采收率在低儲(chǔ)層壓力條件下開發(fā)效果更好,;③CO2置換CH4的效果在低濕度下隨濕度含量增加而得到改善,,對(duì)于干酪根成熟度較高的頁巖儲(chǔ)層,可考慮在氣藏開發(fā)后期注入CO2和一定水蒸氣含量的混合物,。
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關(guān)鍵詞 : CH4吸附, CO2吸附, 競爭吸附, 干酪根, 濕度, 分子模擬
Abstract

  The adsorption behaviors of CH4 and CO2 on moist kerogen are vital to understand the process of CO2sequestration and shale gas exploitation. In this work, a realistic type II dry kerogen model was constructed and optimized by the molecular dynamics (MD) method. Then moist kerogen models with various moisture contents (0.7 wt.%, 1.4 wt.%, 2.1 wt.% and 2.8 wt.%) were developed by Grand Canonical Monte Carlo (GCMC) simulations, and the adsorption characteristics of CH4, CO2 and their mixtures on these kerogen models were investigated. Based on the influences of moisture content on the adsorption capacity, isosteric heat of adsorption and adsorption selectivity of gas molecules, the potential feasibility of CO2 sequestration and enhanced shale gas recovery was discussed. Results show that water molecules are prone to aggregate into cage cluster structures at high moisture content, worsening the replacement effect of CH4 by CO2. The development effect of shale gas reservoirs with CO2 sequestration is better at low reservoir pressure. Moreover, the development effect for CO2 replacing CH4 can be improved by increasing the kerogen moisture content at low moisture conditions. For a shale gas reservoir with higher thermal maturity, it can be beneficial to inject some mixtures of CO2 and a certain amount of steam at the late development stage in order to enhance the shale gas recovery.

Key words: CH4 adsorption CO2 adsorption competitive adsorption kerogen moisture molecular simulation
收稿日期: 2017-04-12 ????
PACS: ? ?
基金資助:國家自然科學(xué)基金“頁巖氣多組分競爭吸附機(jī)理研究”(51774298),、國家自然科學(xué)基金“基于CT掃描及數(shù)字巖心的致密油多尺度滲吸機(jī)理研究”(51504265),、中國石油大學(xué)(北京)優(yōu)秀青年教師研究項(xiàng)目“基于非介入可視化技術(shù)的致密油藏滲吸機(jī)理研究” (2462015YQ0223) 聯(lián)合資助
通訊作者: 寧正福, [email protected]
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黃亮,寧正福,,王慶,,秦慧博,,葉洪濤,張文通,,李鐘原,,孫一丹. 濕度對(duì)CH4/CO2在干酪根中吸附的影響:分子模擬研究[J]. 石油科學(xué)通報(bào), 2017, 2(3): 422-430. HUANG Liang, NING Zhengfu, WANG Qing, QIN Huibo, YE Hongtao, ZHANG Wentong, LI Zhongyuan, SUN Yidan. Effect of moisture on CH4/CO2 adsorption on kerogen: A molecular simulation study. Petroleum Science Bulletin, 2017, 2(3): 422-430.
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