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首頁» 過刊瀏覽» 2016» Vol. 1» Issue (3) 503-511???? DOI : 10.3969/j.issn.2096-1693.2016.03.047
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超重力技術(shù)在蒽醌法制備雙氧水上應(yīng)用的初步探索
呂昀祖,周紅軍,徐泉
中國石油大學(xué)(北京)新能源研究院,,北京 102249
The application of Higee technology in the anthraquinone process for producing hydrogen peroxide
LV Yunzu, ZHOU Hongjun, XU Quan
Institute of New Energy, China University of Petroleum-Beijing, Beijing 102249, China

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摘要? 自主設(shè)計并搭建了一套超重力反應(yīng)裝置以研究超重力技術(shù)在蒽醌法生產(chǎn)雙氧水上的應(yīng)用,。實驗分別考察蒽醌加氫在超重力單程加氫操作和循環(huán)加氫操作下的氫效以及時空收率。實驗結(jié)果表明在超重力反應(yīng)系統(tǒng)中,,當(dāng)轉(zhuǎn)速在350~400 r/min時加氫效率最高,;在40~60 ℃,,0.1~0.3 MPa的條件下,,隨溫度和壓力升高氫效有所提高,。同時實驗發(fā)現(xiàn)在相同反應(yīng)條件下,循環(huán)加氫的操作方法雖然可以得到較高的氫效但同時極大地降低了時空收率,。用超重力技術(shù)單程加氫的操作方法可以得到的產(chǎn)品時空收率為27.9 g(H2O2)/L(cat.)·h,,遠(yuǎn)高于同條件下的采用固定床加氫的產(chǎn)品時空收率(12.7~16.5 g(H2O2)/L(cat.)·h)。因此本文認(rèn)為采用連續(xù)的單程加氫的超重力技術(shù)在蒽醌法制備雙氧水上更具經(jīng)濟性,。
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關(guān)鍵詞 : 超重力技術(shù),; 循環(huán)加氫,; 單程加氫; 蒽醌法,; 雙氧水制備
Abstract

  This paper describes Higee(High Gravity) technology which produces hydrogen peroxide with an independently designed and constructed Higee reaction system in the anthraquinone process. This Higee equipment consists of 5 parts: raw material tank, product tank, working pump, temperature-controlled water bath and the rotating packed bed (RPB) reactor. And it is also comprised of two circulatory systems, the raw material heat circulatory system and the working liquid continuous reaction circulatory system. The raw material heat circulatory system comprises a raw material tank, working pump and temperature-controlled water bath. Working fluid pumped from the raw material tank by the working pump flows back to the raw material tank through the temperature-controlled water bath achieving a rapid heating cycle of the working fluid. The working liquid continuous reaction circulatory system includes all those 5 parts. Working fluid is pumped from raw material tank, and then raw material flows back through temperature-controlled water bath, Higee reactor and product tank. This whole process is called the working fluid continuous reaction. The experimental results show that the appropriate rotation speed has improved the hydrogenation efficiency significantly, and the optimum speed is 350~400 r/min. Simultaneously, the effect of temperature and pressure on the Higee reaction system is similar to that of a fixed bed reactor system. Circulatory hydrogenation operation can achieve a higher hydrogenation efficiency, and in the meanwhile greatly reduce the space-time yield. Compared with the fixed bed production technology (12.7~16.5 g(H2O2)/L(cat.)·h), Higee production technology by one-way hydrogenation has a higher space-time yield (27.9 g(H2O2)/L(cat.)·h), and therefore successive one-way hydrogenation is more economical and has more research value.

Key words: Higee technology ; cyclic hydrogenation ; one-way hydrogenation ; anthraquinone process ; hydrogen peroxide preparation
收稿日期: 2016-09-11 ????
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通訊作者: [email protected]
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呂昀祖,,周紅軍,徐泉. 超重力技術(shù)在蒽醌法制備雙氧水上應(yīng)用的初步探索[J]. 石油科學(xué)通報, 2016, 1(3): 503-511. LV Yunzu, ZHOU Hongjun, XU Quan. The application of Higee technology in the anthraquinone process for producing hydrogen peroxide. 石油科學(xué)通報, 2016, 1(3): 503-511.
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